Solution 1:
Add Unique Index on your table:
ALTER IGNORE TABLE `TableA`
ADD UNIQUE INDEX (`member_id`, `quiz_num`, `question_num`, `answer_num`);
Solution 2:
Add primry key in your table then you can easily remove duplicates from your table using below query:
DELETE FROM member
WHERE id IN (SELECT *
FROM (SELECT id FROM member
GROUP BY member_id, quiz_num, question_num, answer_num HAVING (COUNT(*) > 1)
) AS A
);